The sky appears a glorious pink/red when aerosols (small particles) in the atmosphere preferentially scatter the blue part of the Sun's light spectrum, meaning our eyes receive a more reddish colour from the sky. The preferential scattering requires a low incident angle from the Sun, hence why this phenomena occurs at sunrise or sunset. Also required are the small atmospheric particles, which often exist in greater concentrations when high pressure dominates.
If there is red sky whilst the sun sets in the west, there is likely to be high pressure to the west of our location. If the high pressure is moving east it will soon reach our location, often bringing pleasant, stable conditions with it - a shepherd's delight. Because weather systems predominantly come from the west in the UK, red sky at night is often followed by high pressure and calm weather.
| Red sky at night over the University of Leeds on 30/11/16. |
| Red sky in the morning over Leeds on 05/12/16 |
Nevertheless, this saying, like other old weather proverbs and stories, give us an idea of what weather forecasting consisted of before today's meteorological understanding and accuracy.